chemistryRP5 · Rate and Extent of Chemical ChangePaper 2Combined and Separate

Rates of reaction

Method overview

Use either gas collection/mass loss for acid–carbonate or disappearance of a cross for thiosulfate. Change one factor, start timing on mixing, record at fixed intervals or a defined endpoint, repeat and compare rates.

Apparatus set-up

Diagram
Acid + marble chips
Gas syringe
Stopwatch

conical flask; gas syringe; balance; stopwatch; acid; marble chips; sodium thiosulfate; cross; measuring cylinders

Independent variable

concentration or surface area

Dependent variable

gas volume/mass loss/turbidity time and rate

Control variables

temperature; reactant amounts; apparatus; total volume; endpoint

Apparatus

conical flask; gas syringe; balance; stopwatch; acid; marble chips; sodium thiosulfate; cross; measuring cylinders

Safety

Wear eye protection; acids irritate; sulfur dioxide from thiosulfate should be produced on small scale in ventilation.

Scientific rationale

Higher concentration or surface area increases collision frequency; higher temperature increases collision frequency and fraction above activation energy.

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